Journal
ORGANIC LETTERS
Volume 19, Issue 19, Pages 5486-5489Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02877
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Funding
- CSIR, India [01(281.5)/14/EMR-II]
- VIT University, Vellore
- UGC, India [F.2-4/2011 (SA-I)]
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N-Acylsaccharin represents a facile acyl group transfer agent to heteroarenes in the presence of Pd(II)/NHC complexes appended with a pyrene unit. Catalytic acylation of heteroarenes was enhanced by the noncovalent interaction between the pyrene unit and substrates. High functional group tolerance, broad substrate scope, and moderate to good yields of 2-acylated azoles are added features of this method.
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