Journal
ORGANIC LETTERS
Volume 19, Issue 19, Pages 5482-5485Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02861
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Funding
- IISER Mohali
- CSIR, New Delhi
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An operationally straightforward organocatalytic beta-azidation of alpha,beta-unsaturated ketones is described. Reaction of the Zhdankin azidoiodane with enones in the presence of a catalytic amount of an amine provides beta-azido ketones via the formation of an electron-donor acceptor complex. The application of this protocol is demonstrated through one-step elaborations leading to the synthesis of unprecedented classes of 1,2,3-triazoles.
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