Journal
ORGANIC LETTERS
Volume 19, Issue 11, Pages 3009-3012Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01270
Keywords
-
Categories
Funding
- Ministry of Science and Technology of China [2013CB834804, 2014CB239402, 2013CB834505]
- National Natural Science Foundation of China [21390404, 91427303]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB17030400]
- Chinese Academy of Sciences
Ask authors/readers for more resources
The excellent oxidizing capability of acridinium-based organic dye (Acr(+)-Mes) is fully studied in photoredox catalysis. However, its reducing ability is always considered weak for organic transformation. The reducing ability of Acr(+)-Mes is developed by Selectfluor to achieve effective fluorination and oxidation of benzylic C(sp(3))-H bonds under visible light irradiation, which is not available for the direct use of oxidizing ability of excited Acr(+)-Mes. Mechanistic insights provided strong evidence for the oxidative quenching of Acr(+)-Mes.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
