Journal
ORGANIC LETTERS
Volume 19, Issue 16, Pages 4403-4406Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b02175
Keywords
-
Categories
Funding
- DST-SERB, India [EMR/2016/004040]
- CSIR-New Delhi
- UGC-New Delhi
- UT Madras-Chennai
Ask authors/readers for more resources
An efficient.one-pot method for the stereoselective synthesis of novel iminosugar C-nitromethyl glycosides is described. This new class of iminosugar glycoidesides vetsatile nitromethyl functionality whose utility was further demonstrated in the single-step synthesis of bicyclic iminosugars Under reagent-free conditions the N-ally]-C-nitromethyl glycosides resulted in intramolecular cyclization to iminosugar-oximes, whereas under SET oxidation, they furniShed cyclopropane-fused iminosugar. The N-propargyl-C-nitromethyl glycosides underwent an unprecedented ketenimine-acrylamidine-Michael addition cascade reaction to give bicyclic amidines.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available