Journal
ORGANIC LETTERS
Volume 19, Issue 11, Pages 3029-3032Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01323
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Funding
- National Natural Science Foundation of China [31370372]
- Foundation of the Key Laboratory of Plant Resources and Chemistry in Arid Regions, Xinjiang Technical Institute of Physics and Chemistry, CAS [2008DP173091-2016-01]
- Fundamental Research Funds for the Central Universities [HUST: 2016YXMS148]
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Two diterpenoids with an unprecedented diterpene carbon skeleton, cinnamomols A (1) and B (2), were isolated from the leaves of Cinnamomum cassia. 1 and 2 feature a cage-like, rigid, 5/5/5/5/5/6-fused hexacyclic ring system. The structures of 1 and 2 were established by extensive spectroscopic techniques and single-crystal X-ray diffraction, and their plausible biosynthetic pathways were proposed. 1 and 2 exhibited significant in vitro immunostimulative activity, and the mode of action of 1 was investigated.
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