Journal
ORGANIC LETTERS
Volume 19, Issue 15, Pages 3947-3949Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01608
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An efficient copper-catalyzed synthesis of substituted 2,4-diamino-1,3,5-triazines from 1,1-dibromoalkenes and biguanides under mild conditions has been developed. The reaction occurred in moderate to good yields and tolerated alkyl-, heterocyclic-, or aryl-substituted 1,1-dibromoalkenes containing functionalities such as nitriles, ethers, and halogens. Monosubstituted to tetrasubstituted biguanidines also afforded the desired products.
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