Journal
ORGANIC LETTERS
Volume 19, Issue 22, Pages 6144-6147Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03022
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Funding
- National Research Foundation of Korea (NRF) - Korean government (MEST) [NRF-2016R1A4A1011451, NRF-2016R1A2B4011719]
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A copper-catalyzed, enantioselective method for the borylallylation,of vinyl arenes is reported. The reaction produces enantioenriched and functiorialized organoboron-compounds by sequentially incorporating boryl, and ally: groups onto the C=C bond of vinyl arenes. Copper-catalyzed borylative coupling of vinyl arenes with ally phosphates successfully proceeds in a regio- and enantioselective manner in the absence of a palladium cocatalyst.
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