Journal
ORGANIC LETTERS
Volume 20, Issue 1, Pages 272-275Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b03663
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Funding
- National Natural Science Foundation of China [21602253, 81673301]
- Natural Science Foundation of Jiangsu Province [BK20160749]
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An unprecedented rhodium-catalyzed homocoupling reaction of gamma-alkylated tert-propargylic alcohols is reported, and 2-alkynylated buta-1,3-diene or 2-alkynylated hexa-1,3,5-triene are generated selectively. Multiple beta-eliminations, including sequential beta-carbon, beta-hydrogen, and beta-oxygen eliminations from the corresponding rhodium intermediates, are assumed to be involved during the reaction process.
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