Journal
ORGANIC ELECTRONICS
Volume 41, Issue -, Pages 362-368Publisher
ELSEVIER
DOI: 10.1016/j.orgel.2016.11.029
Keywords
Polymer solar cells; Back electrode; Micro-nanostructure; Power conversion efficiency
Funding
- Fundamental Research Funds for the Central Universities [2014JBZ009]
- National Natural Science Foundation of China [61274063, 61377028, 61475014, 61675018]
- Scientific Research Common Program of Beijing Municipal Commission of Education [SQKM201710011009, KM201510011002]
- Natural Science Cultivation Fund of Beijing Technology and Business University [LKJJ2016-24]
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The formation of a micro-nanostructured back electrode provides an efficient route for enhancing light absorption in polymer solar cells by light scattering of the bumpy electrode. In this study, we incorporated propylene glycol mono-methyl ether acetate (PGMEA) into the poly (3-hexylthiophene) (P3HT) and [ 6: 6]-phenyl-C61-butyric acid (PC61BM) solution, and the PGMEA induced P3HT aggregations give rise to a bumpy surface of the active layer. The sequential deposition of the Al electrode onto the active layer creates a polymer solar cell with interpenetrated micro-nanostructured morphology of the active layer/electrode interface. The higher crystallinity of P3HT induced by active layer self-aggregation improves carrier mobility. The bumpy active layer/electrode interface can not only facilitate charge carriers transfer and collection in the device, but also enhance optical scattering and leads to enhanced light absorption of the active layer. The resulting device shows improved photocurrent, corresponding to power conversion efficiency improvement of 17.9% as compared to the planar device. This work indicates that the active layer self-aggregation is a simple, cost-effective and mold-free methodology to manufacture high performance polymer solar cells with the micro-nanostructured back electrode. (C) 2016 Elsevier B.V. All rights reserved.
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