Journal
ORGANIC ELECTRONICS
Volume 45, Issue -, Pages 115-123Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.orgel.2017.03.001
Keywords
Photodiodes; Organic-inorganic interface; ZnO; Conjugated polymers; Capacitance-voltage
Funding
- US National Science Foundation [ECCS-1305642]
- Department of Science and Technology for Swarnajayanti Fellowship
- Div Of Electrical, Commun & Cyber Sys
- Directorate For Engineering [1305642] Funding Source: National Science Foundation
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Hybrid organic-inorganic photodiode interfaces have gained significant interest due to their unique physical properties such as mechanical flexibility and high photosensitivity. Two diketopyrrolopyrrole (DPP)-based donor-acceptor copolymers with different backbone conformations are characterized in an inverted non-fullerene photodiode architecture using ZnO nano-patterned films as the electron transport layer. The DPP copolymer with a thienothiophene unit (PBDT-TIDPP) is more planar and rigid compared to the DPP system with a thiophene unit connecting the donor and acceptor moieties within the monomer (PBDT-TDPP). The hybrid interfaces were optimized by using poly(3-hexylthiophene) (P3HT) as the p-type layer for monitoring the critical thickness and morphology of the ZnO layer. The maximum photoresponsivity from a P3HT:ZnO photodiode was found to be 56 mA/W. The photoresponsivity of PBDT-TTDPP:ZnO photodiodes were found to be more than two orders of magnitude higher than PBDT-TDPP:ZnO photodiodes, which is attributed to an enhanced transport of carriers due to the planar backbone conformation of the PBDT-TTDPP copolymer. Capacitance-voltage measurements from hybrid Schottky barrier interfaces further shed light into the nature of photocarriers and device parameters. First-principles time-dependent density-functional theoretical calculations yield a higher absorptivity for the PBDT-TTDPP dimer compared to PBDT-TDPP. (C) 2017 Elsevier B.V. All rights reserved.
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