Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 15, Issue 8, Pages 1771-1775Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob00203c
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Funding
- Swedish Research Council (VR)
- Carl Trygger Foundation
- Wenner-Gren Foundation
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A redox-economical strategy for the synthesis of trifluoromethylated enamides using copper catalysis is reported. The reaction employs the inexpensive Langlois reagent (CF3SO2Na) and takes place without the need of an external oxidant. The trifluoromethylated enamide products can easily be converted into the corresponding ketone, saturated amide or oxazole.
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