Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 15, Issue 45, Pages 9680-9684Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob02579c
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Funding
- Ministerio de Economia y Competitividad [MAT2016-78625-C2-2-P, MAT2015-71727-R]
- Universidad de Alicante [VIGROB-173]
- Instituto de Sintesis Organica (ISO)
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We report on the use of visible light photoredox catalysis for the radical Smiles rearrangement of 2-aryloxybenzoic acids to obtain aryl salicylates. The method is free of noble metals and operationally simple and the reaction can be run under mild batch or flow conditions. Being a redox neutral process, no stoichiometric oxidants or reductants are needed.
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