Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 15, Issue 37, Pages 7909-7916Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob01742a
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Funding
- Major Basic Research Project of the Natural Science Foundation of the Jiangsu Higher Education Institutions [15KJA150006]
- National Natural Science Foundation of China [21502074]
- College Students Practice Innovation Training Plan of Jiangsu Province of China [201711463010Z]
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A concise and efficient approach to design and synthesize hetero[5] helicene-like molecules and coumarin derivatives is reported. Intriguingly, using the same catalyst ( silica sulfuric acid), and a different solvent and reaction temperature, the reaction selectively afforded hetero[5] helicene-like molecules 3 or coumarin derivatives 4. Product 4 has a highly planar geometry, and product 3 can be regarded as hetero[5] helicenelike because of its helical conformation.
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