Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 15, Issue 5, Pages 1086-1090Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob02691e
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A transition metal-free synthesis of N-cyanosulfoximines from sulfoxides using N-chlorosuccinimide (NCS) as oxidising agent and cyanamide as nucleophilic amine source is reported. The products are obtained in moderate to excellent yields. The protocol enables an easy access to N-cyanosulfoximines from readily available starting materials under inversion of configuration at a preexisting stereogenic center.
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