Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 15, Issue 36, Pages 7509-7512Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob01726j
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Funding
- National Basic Research Program of China [2015CB856500]
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A highly efficient synthesis of 4-benzylpyridines was developed via Pd-catalyzed C(sp(3))-H arylation between 4-picoline and aryl halides. It was found that the best yields were achieved with a simple Pd(PPh3)(4) catalyst and Cs2CO3 as the base. Compared with the known methods, our reaction does not require the use of a strong organometallic reagent as the base.
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