Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 15, Issue 38, Pages 8009-8012Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob02126g
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Funding
- National Natural Science Foundation of China [21202041, 51402101]
- Natural Science Foundation of Hunan Province [2017JJ2008]
- Aid Programs for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province
- Key Discipline of Hunan Province
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A room-temperature and PTC-free copper-catalyzed N-arylation of aliphatic amines in neat water has been developed. Using a combination of CuI and 6,7-dihydroquinolin-8(5H)-one oxime as the catalyst and KOH as the base, a wide range of aliphatic amines are arylated with various aryl and heteroaryl halides to give the corresponding products in up to 95% yield.
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