Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 15, Issue 44, Pages 9288-9292Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7ob02491f
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Funding
- National Natural Science Foundation of China [21603150]
- Shihezi University [RCZX201543, CXRC201602]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT_15R46]
- Yangtze River Scholar Research Project of Shihezi University [CJXZ201601]
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Chemoselective N-arylation of unprotected aminobenzamides was achieved via Cu-catalysed Chan-Evans-Lam cross-coupling with aryl boronic acids for the first time. Simple copper catalysts enable the selective arylation of amino groups in ortho/meta/para-amino-benzamides under open-flask conditions. The reactions were scalable and compatible with a wide range of functional groups.
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