4.7 Article

Cyclic ultracapacitor for fast-charging and scalable energy storage system

Journal

ENERGY
Volume 93, Issue -, Pages 210-219

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.energy.2015.09.037

Keywords

Supercapacitor; Slurry electrode; Porous carbon; Electrochemical flow capacitor

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ESSs (Energy storage systems) for large-scale grid systems and next generation secondary battery systems require an ideal device that satisfies diverse properties such as a high energy density, high power density, low cost, and safe and reliable performance. In this study, we present a CUCap (cyclic ultracapacitor), which is comprised of two reservoirs and one flat flow capacitor cell with a cyclic continuous flow mode and independently tunable power rating and energy capacity. CUCap provides fast-charging and high capacity technology with a simple and practical design for high density and large-scale energy storage systems. The best performance appeared in slurry ratio (electrode to electrolyte) 1 to 7 with the total reservoir volume of 150 mL and the flow rate 300 ml/min, resulting in volumetric energy density, specific capacitance, and discharge time of 7.7 Wh L-1, 14.2 F ml(-1), 100 min, respectively. Moreover, the slurry electrode of the CUCap cell had a maximum current density around 260 mA cm(-2) which could possibly result in a fast-charging CUCap system. (C) 2015 Elsevier Ltd. All rights reserved.

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