Journal
OPTICAL MATERIALS
Volume 64, Issue -, Pages 58-63Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.optmat.2016.11.031
Keywords
Up-conversion luminescence; Core-shell structure; Y2O2S:Er3+@Y2O2S:Yb3+,Tm3+; Homogeneous co-precipitation method
Categories
Funding
- Research Program of Application Foundation (Main subject) of Ministry of Transport of PR China [2015329225090]
- National Natural Science Foundation of China [11504039, 1502031]
- Liaoning Provincial Natural Science Foundation of China [2015020206]
- Fundamental Research Funds for the Central Universities [3132016120, 3132016221, 3132016222, 3132016349]
- Foundation of Liaoning Educational Committee [L2013201, L2014208, L2014212]
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The Y2O2S:Er3+@Y2O2S:Yb3+,Tm3+ core-shell upconversion (UC) nanoparticles with average diameter of 95 nm were synthesized by the homogeneous co-precipitation method combining with the solid-gas sulfidation route. The increases of nanocrystaline size after the shell coating was observed both in the X-ray diffraction (XRD) and transmission electron microscope (TEM) measurements. This indicates the composition homogeneity core-shell Y2O2S nanocrystals. Meanwhile, the luminescence of both the Er3+ and Tm3+ ions are realized for the first time in the novel core-shell Y2O2S:Er3+@Y2O2S:Yb3+,Tm3+ nanoparticles under the excitations of both 980 and 1550 nm. When excited by a 980 nm laser diode, the Y2O2S:Er3+@Y2O2S:Yb3+,Tm3+ phosphor exhibits blue (approximate to 475 nm), green (approximate to 548 nm) and red (approximate to 670 nm) emissions in the visible region, which correspond to the (1)G(4) -> H-3(6) transition of Tm(3+)ions, S-4(3/2), H-2(11/2) -> I-4(15/2) and F-4(9/2) -> I-4(15/2) transitions of Er3+ ions, respectively. The very strong emission at the near infrared (NIR) region is mainly due to the H-3(4) -> H-3(6) transition of Tm3+ ions. The emission from both of Era} and Tm3+ ions under 980 nm excitation reveals the energy transfers of Yb3+ -> Tm3+ within the shell layer and Yb3+ -> Er3+ between the shell and the core. When pumping at 1550 nm, although only Er3+ ions can efficiently absorb the excitation energy, the strong UC emissions from Tm3+ ions were also observed. This is owing to the energy transfer between the core and the shell through Er3+ -> Yb3+ -> Tm3+ ions. (C) 2016 Elsevier B.V. All rights reserved.
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