4.2 Article

PdCu/Al2O3 catalyst for Sonogashira cross-coupling: effect of a Pd/Cu ratio on the catalytic performance

Journal

MENDELEEV COMMUNICATIONS
Volume 28, Issue 5, Pages 538-540

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/j.mencom.2018.09.030

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Funding

  1. Russian Science Foundation [16-13-10530]
  2. Russian Science Foundation [16-13-10530] Funding Source: Russian Science Foundation

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The catalytic performance of 3 wt% Pd Cu/Al2O3 containing bimetallic alloy Pd-Cu nanoparticles strongly depends on the Pd/Cu ratio in the cross-coupling of phenylacetylene with phenyl iodide, and a maximum activity is attained at Pd/Cu = 1:2.

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