Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 5, Issue 23, Pages 3443-3446Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo01046c
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Funding
- National Natural Science Foundation of China [21302134]
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A visible-light-mediated radical allylation of primary amine-derived Katritzky salts with allylic sulfones via C(sp(3))-N bond activation is reported, furnishing the corresponding alkenes in satisfactory yields. This mild protocol provides an efficient strategy for site-specific C(sp(3))-C(sp(3)) bond formation using abundant feedstock primary amines, particularly -amino acids as alkyl radical precursors. This photocatalytic reaction demonstrates a broad substrate scope and good functional group tolerance.
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