Journal
ORGANIC CHEMISTRY FRONTIERS
Volume 5, Issue 23, Pages 3406-3409Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8qo00947c
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Funding
- NSFC [21525208, 21472186]
- Henan Normal University [5101034011009]
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Rh(iii)-Catalyzed -fluoroalkenylation of N-nitrosoanilines with 2,2-difluorovinyl tosylates has been realized. This reaction proceeded via chelation-assisted C-H activation, olefin insertion and -F elimination, leading to the synthesis of monofluoroalkenes with high Z-selectivity with respect to the olefin. This catalytic system is highly efficient over a broad range of substrates under mild and redox-neutral conditions.
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