Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 98, Pages 13837-13840Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07746k
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Funding
- Russian Science Foundation [18-13-00058]
- Russian Foundation for Basic Research [17-03-00656]
- Russian Science Foundation [18-13-00058] Funding Source: Russian Science Foundation
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Tungsten trioxide has been found to be a convenient precursor for the synthesis of metal cluster compounds with new types of cluster cores. The reaction between WO3 and KCN led to the formation of the cluster complex [{W-6((4)-O)(2)((3)-CCN)(4)}(CN)(16)](10-). Unexpectedly, it includes the fully deprotonated form of acetonitrile, the CCN3- anion, as a (3)-bridging ligand coordinated to the trigonal faces of the bitetrahedral W-6 metallocluster. A similar complex [{W-6((4)-O)(2)((3)-As)(4)}(CN)(16)](10-) containing (3)-As3- ligands instead of (3)-CCN3- ones has been synthesized by the reaction between WO3, As and KCN.
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