Journal
CHEMICAL COMMUNICATIONS
Volume 54, Issue 95, Pages 13391-13394Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07227b
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The dinuclear mesocate [Fe2L3](BF4)(4), 1, is a supramolecular building block for a microporous material. Structural analysis reveals that extensive noncovalent interactions in the solid state generate a 3D framework with microporous channels. These channels are permanently accessible to incoming guest molecules and adsorption isotherms demonstrate that the material has a high selectivity for CO2 over N-2.
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