Journal
ARABIAN JOURNAL FOR SCIENCE AND ENGINEERING
Volume 43, Issue 5, Pages 2227-2235Publisher
SPRINGER HEIDELBERG
DOI: 10.1007/s13369-017-2632-x
Keywords
Phenol; Wastewater; Fenton; Nano-haematite; RSM
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Phenolic compounds are priority chemicals which, when discharged in wastewater, need to be removed. Photochemical treatment has been demonstrated to be very effective for this task. This paper reports a study to assess the potential of a nano-photo-Fenton-like reagent (NFLR), based on synthesized haematite (- nano-crystalline powder, to remove phenol from wastewater. The use of haematite nano-structures as a source of in NFLR provides a novel and low-cost nano-catalysis treatment of phenol wastewater. The study evaluated the effect of the initial concentration of the phenol pollutant (200-1000 mg/L), and the photo-Fenton parameters such as the nano-haematite and concentrations (100-800 mg/L) and pH range from 2 to 8. NFLR was able to remove about 98% of phenol in about 20 min from a solution initially containing 400 ppm of phenol. Furthermore, a Box-Behnken factorial design was applied to optimize the operating NFLR parameters. The optimum conditions for phenol removal were shown to be 398 mg/L for , 41 mg/L for and 3.25 for pH. The degradation obtained using a response surface methodology is compared with that recorded experimentally at the optimized values. The NFLR, based on nano-haematite, was found to be an effective treatment for the removal of phenol from wastewater.
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