Journal
CATALYSIS LETTERS
Volume 148, Issue 3, Pages 787-812Publisher
SPRINGER
DOI: 10.1007/s10562-017-2273-4
Keywords
Biocatalysis; Enzymes; Hydroxylation; C-H bond activation; Fatty acid; Cytochrome P450
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Cytochrome P450 enzymes catalyze a broad set of C-H activation reactions, the most prominent being hydroxylation. This review provides an overview of the regioselectivity (CH3-terminal, in-chain, and carboxylate-terminal) and the optical purity of the hydroxylation products obtained from fatty acids as far as described, focusing on systems close to preparative application. [GRAPHICS]
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