4.7 Article

Tetrahedral metal-organic cages with cube-like cavities for selective encapsulation of fullerene guests and their spin-crossover properties

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 89, Pages 12646-12649

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc06652c

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Funding

  1. National Natural Science Foundation of China [21771089]
  2. Fundamental Research Funds for the Central Universities [JUSRP51725B, JUSRP51513]
  3. Project for Jiangsu Scientific and Technological Innovation Team
  4. MOE & SAFEA for the 111 Project [B13025]

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Tetrahedral FeII4L(6) coordination cages containing organic linkers with rigid -electron aromatic rings and flexible alkyl units were constructed. Interestingly, these tetrahedral cages have rare cube-like cavities for selective encapsulation of fullerene guests. In addition, the solid state spin-crossover properties were influenced by guest binding of fullerene C-60.

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