Journal
CHEMICAL ENGINEERING & TECHNOLOGY
Volume 41, Issue 3, Pages 496-503Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ceat.201700103
Keywords
Biomass; Bio-purification; H-Cube; Maize stover; Yeast
Categories
Funding
- Hungarian National Research, Development and Innovation Office (NKFIH) [OTKA PD-108389, OTKA PD-121024]
- New Hungary Development Plan [TAMOP-4.2.1/B-09/1/KMR-2010-0002]
- European Union [VEKOP-2.3.2-16-2017-00013]
- State of Hungary - European Regional Development Fund
- National Research, Development and Innovation Fund of Hungary [FIEK_16-1-2016-0007]
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Xylitol is produced by the heterogeneous catalytic hydrogenation of xylose over Raney nickel. The hydrogenation must typically be followed by several purification steps, which makes the chemical production relatively complex and expensive. In this study, activated carbon and bio-purification treatments of corn stover hydrolysates and subsequent nickel-catalyzed hydrogenation of xylose to xylitol were investigated. The activated carbon treatment was used to eliminate inhibitory compounds and increase the efficiency of the bio-purification step. It was found that the glucose could be completely eliminated from the hydrolysate. The hydrogenation reactions of corn stover hydrolysate demonstrated that a high reaction temperature resulted in high sugar alcohol yields and selectivity. At a given temperature, the flow rate had no significant effect on xylitol yield.
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