Li8NaRb3(SO4)6•2H2O as a new sulfate deep-ultraviolet nonlinear optical material

Sulfates have long been ignored as nonlinear optical materials over the past decades. Here we report a new sulfate deep-ultraviolet nonlinear optical material Li8NaRb3(SO4)(6)center dot 2H(2)O synthesized by the facile water solution method. It crystallizes in the asymmetric monoclinic space group C2 (No. 5). Its single-crystal structure features a three-dimensional framework made up of SO4 and LiO4 tetrahedra. Powder second-harmonic generation tests demonstrate that Li8NaRb3(SO4)(6)center dot 2H(2)O is phase-matchable with a second-harmonic generation response of about 0.5 x KH2PO4. Ultraviolet-visible-near-infrared diffuse reflectance spectra illustrate that the ultraviolet cutoff edge of Li8NaRb3(SO4)(6)center dot 2H(2)O may be as low as lambda < 190 nm. Theoretical calculations reveal that the optical properties of Li8NaRb3(SO4)(6)center dot 2H(2)O are mainly attributed to S-O groups. All these results reveal that Li8NaRb3(SO4)(6)center dot 2H(2)O may possess potential use in the deep-ultraviolet nonlinear optics field. We believe that the discoveries in our work will attract scientists' attention to sulfate systems for their potential as deep-ultraviolet nonlinear optical materials.