4.7 Article

A homochiral Zn-Dy heterometallic left-handed helical chain complex without chiral ligands: anion-induced assembly and multifunctional integration

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 95, Pages 13379-13382

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07468b

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Both second-order nonlinear optical and single-molecule magnet properties are observed in a novel 1D homochiral Zn-Dy heterometallic left-handed helical chain complex (1) without chiral ligands, which evolves from a Zn3Dy2 pentanuclear cluster complex (2), thanks to the structural guiding role of perchlorate anions.

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