Journal
CHINESE JOURNAL OF CATALYSIS
Volume 39, Issue 8, Pages 1294-1302Publisher
SCIENCE PRESS
DOI: 10.1016/S1872-2067(18)63086-4
Keywords
Carbon dioxide hydrogenation; Long-chain hydrocarbons; Carbon dioxide Fischer-Tropsch synthesis; Alkali metal promoters; Cobalt-copper based catalysts
Funding
- Frontier Science Program of Shell Global Solutions International B. V. [PT65197]
- National Natural Science Foundation of China [21773286, 21503260, 21776296]
- Youth Innovation Promotion Association CAS [20178330]
- Transformational Technologies for Clean Energy and Demonstration, Strategic Priority Research Program of the Chinese Academy of Sciences [XDA21090204]
- Shanghai Municipal Science and Technology Commission, China [16DZ1206900]
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CoCu/TiO2 catalysts promoted using alkali metals (Li, Na, K, Rb, and Cs) were prepared by the homogeneous deposition-precipitation method followed by the incipient wetness impregnation method. The influences of the alkali metals on the physicochemical properties of the CoCu/TiO2 catalysts and the catalytic performance for CO2 hydrogenation to long-chain hydrocarbons (Cs.) were investigated in this work. According to the characterization of the catalysts based on X-ray photoelectron spectroscopy, X-ray diffraction, CO2 temperature-programmed desorption (TPD), and H-2-TPD, the introduction of alkali metals could increase the CO2 adsorption and decrease the H-2 chemisorption, which could suppress the formation of CH4, enhance the production of C5+, and decrease the hydrogenation activity. Among all the promoters, the Na-modified CoCu/TiO2 catalyst provided the maximum Cs. yield of 5.4%, with a CO2 conversion of 18.4% and Cs. selectivity of 42.1%, because it showed the strongest basicity and a slight decrease in the amount of H-2 desorption; it also exhibited excellent catalytic stability of more than 200 h. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
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