Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 16, Issue 48, Pages 9368-9372Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ob01262h
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Funding
- National Science Foundation [CHE-1554906]
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Iron-catalyzed hydrosilylation of imines to amines using a well-defined iron complex is reported. This method employs relatively mild conditions, by reaction of imine, (EtO)(3)SiH in a 1:2 ratio in the presence of 1 mol% precatalyst ([BIAN]Fe((6)-toluene), 3, BIAN = bis(2,6-diisopropylaniline)acenaphthene) at 70 degrees C. A broad scope of imines was readily converted into the corresponding secondary amines without the need for precatalyst activators.
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