Journal
NEW JOURNAL OF CHEMISTRY
Volume 41, Issue 9, Pages 3508-3514Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6nj03876j
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- National Natural Science Foundation of China [21371059, 21671068]
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The crystal structure of 5,10,15,20-tetra(ethoxycarbonyl)porphyrin copper(II) showed that its central copper has a six-coordinate structure. An efficient copper porphyrin-catalyzed cross-dehydrogenative coupling (CDC) esterification reaction between C(sp(3))-H and carboxylic acids using di-tert-butyl peroxide (DTBP) as an oxidant was established. The kinetic isotope effect (KIE) indicated that C(sp(3))-H bond cleavage was the rate-determining step of this CDC reaction.
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