4.6 Article

First synthesis of heterocyclic allenes - benzazecine derivatives

Journal

NEW JOURNAL OF CHEMISTRY
Volume 41, Issue 5, Pages 1902-1904

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6nj03403a

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Funding

  1. RF Ministry of Education and Science under the program for improving the competitiveness of RUDN among leading global science-education centers
  2. Russian Foundation for Basic Research [15-33-20187-mol_a_ved, 17-03-00605, 17-53-540001]

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Benzazecines with an allene fragment were prepared for the first time and in high yields via tandem reaction of 1-phenylethynyl-1-methyl(benzyl)-1,2,3,4-tetrahydroisoquinolines with activated alkynes in trifluoroethanol.

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