Journal
NEW JOURNAL OF CHEMISTRY
Volume 41, Issue 10, Pages 3908-3914Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nj00028f
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Funding
- China Scholarship Council
- Toulouse IDEX Emergence program
- CNRS
- CONACyT
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An improved 12-step synthetic route and full characterization of hexaphenyl-carbo-benzene (4, 8%) and the p-bis-3,5-di-tert-butylphenyl homologue (11, 4%), are described. The carbo-benzene reference 4 is now accurately described in the crystal state by X-ray diffraction analysis in the chiral space group P2(1)2(1)2(1), and in comparison to the less symmetric derivative 11 exhibiting a centro-symmetric packing. According to cyclic voltammetry, both hexaaryl-carbo-benzenes 4 and 11 can behave as both reversible potent electron acceptors and standard electron donors, with respective potentials of -0.73 +/- 1 V and +1.17 +/- 2 V/SCE, respectively. Due to their extremely low solubility, solid films of 11 fabricated using the wet method, with the initial view of studying charge transport properties, were found to display high roughness.
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