Journal
NEW JOURNAL OF CHEMISTRY
Volume 41, Issue 8, Pages 3082-3088Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6nj03584a
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Funding
- Faculty of Science of the University of Johannesburg
- National Research Foundation, South Africa
- Global Excellence
- University of Johannesburg
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A graphitic carbon nitride supported copper nanoparticle composite (Cu-gCN) has been found to be an active catalyst for the N-arylation of hetero-aromatic systems (pyrrole, pyrazole, and substituted indole) and benzamide molecules, with high product selectivity and good to excellent yields, using substituted aryl bromide as a coupling partner. The intercalated structure and the amine functional group of the carbon nitride prevent the aggregation of the catalytically active copper species during the reaction, and the recyclability study shows the stable performance of the catalyst without a significant loss of catalytic activity.
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