4.6 Article

Pyridine-functionalized organic porous polymers: applications in efficient CO2 adsorption and conversion

Journal

NEW JOURNAL OF CHEMISTRY
Volume 41, Issue 8, Pages 2869-2872

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6nj03899a

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Funding

  1. National Natural Science Foundation of China [21402208, 21533011, 21125314]

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Pyridine-functionalized porous organic polymers showed excellent CO2 uptake capacity (up to 63 and 171 mg g(-1) at 0.1 and 1 bar at 273 K), and performed well as supports for Ru(0) nanoparticles. The resultant CarPy-CMP@Ru served as an efficient catalyst for the formylation of amines with CO2/H-2, together with high product yields (89-93%), high stability and easy recyclability.

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