Journal
NEW JOURNAL OF CHEMISTRY
Volume 41, Issue 4, Pages 1820-1826Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6nj03345h
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- Russian Government
- Russian Foundation for Basic Research [15-03-02877]
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For the first time, monofunctionalized pillar[5] arenes containing a 1-aminophosphonate fragment have been obtained and characterized. As shown by NMR spectroscopy, the replacement of the amino groups by 1-aminophosphonate units in the macrocycle structure allows switching of self-assemblinghost- guest complexation'' properties of the monofunctionalized pillar[5] arenes. Thus, new synthesized aminophosphonated pillar[5] arenes form host-guest complexes with aliphatic amines contrary to monoamine macrocycles that tend to self-assemble.
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