Journal
ACS OMEGA
Volume 3, Issue 12, Pages 17155-17163Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.8b02480
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Funding
- CSIR
- DST [EMR/2017/0002413]
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A facile route to 3-sulfonylated and 3-(1-benzotriazolyl)-benzofurans is achieved from readily available o-hydroxyphenyl propargyl alcohols (o-HPPAs) and bench-top sodium sulfonylates and benzotriazoles with no assistance of any reagent or catalyst. Bifunctional o-quinone methides (o-QMs) were the putative reaction intermediates ensued from dehydration of o-HPPA. Our study revealed that the o-QM was so choosy in selection of the nucleophiles for the key Michael addition reaction.
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