Journal
ACS OMEGA
Volume 3, Issue 12, Pages 18002-18015Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.8b02966
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Funding
- National Natural Science Foundation of China [21272004, 21702237]
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An operationally simple, efficient, and metal-/peroxide-free three-component reaction of alkynes, iodine, and sodium sulfinates has been developed for the construction of highly functionalized tetrasubstituted alkenes. Iodo- and sulfonyl-containing tetrasubstituted alkenes, such as vinyl ketones, allylic alcohols, and conjugated enynes, could be obtained regio- and stereoselectively in up to 96% yield.
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