Journal
RADIOCHEMISTRY
Volume 60, Issue 6, Pages 595-600Publisher
PLEIADES PUBLISHING INC
DOI: 10.1134/S106636221806005X
Keywords
m-nitrobenzotrifluoride; diamides of 2; 6-pyridinedicarboxylic and 2; 2'-bipyridine-6; 6'-dicarboxylic acids; extraction system; irradiation; thermolysis; gas evolution
Funding
- Russian Science Foundation [16-19-00191]
- Russian Science Foundation [16-19-00191] Funding Source: Russian Science Foundation
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The dynamics of gas evolution in thermal oxidation of solutions of 2,2'-bipyridine-6,6'-dicarboxylic acid di(N-ethyl-4-hexylanilide) (DYP-7), 2,6-pyridinedicarboxylic acid di(N-ethyl-4-fluoroanilide) [Et(pFPh) DPA], and 2,2'-bipyridine-6,6'-dicarboxylic acid di(N-ethyl-4-ethylanilide) (DYP-9) in m-nitrobenzotrifluoride (F-3) diluent with 14 M HNO3 in open and closed vessels was studied. The effect of preliminary irradiation of the organic phase on the kinetics of thermolysis of the two-phase system was determined. Heating of the irradiated samples in a closed vessel (autoclave) leads to the pressure buildup, with the pressure reached increasing from 18 to 23 atm as the absorbed dose is increased from 0 to 1 MGy. The exothermic processes occurring in the systems caused a 4 to 10 degrees C increase in the sample temperature. The thermal stability of all the irradiated diamide-F-3 diluent extraction systems studied is acceptable for practical use.
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