Journal
RSC ADVANCES
Volume 8, Issue 73, Pages 42223-42232Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c8ra08908f
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Funding
- National Key R&D Program of China [2017YFB0102102]
- National Natural Science Foundation of China [51674228]
- Fundamental Research Funds for the Central Universities [WK2320000038]
- External Cooperation Program of BIC, CAS [211134KYSB20150004]
- Youth Innovation Promotion Association CAS [2013286]
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Currently, the effective and prompt suppression of lithium-ion battery fires is still challenging. Herein, a 38 Ah prismatic ternary (Li(Ni1/3Co1/3Mn1/3)O2/graphite) battery with the size of 150 x 92 x 27 mm3 was adopted to investigate the suppression efficiency of dodecafluoro-2-methylpentan-3-one (C6F12O) in high capacity lithium-ion battery fires. Five doses of C6F12O agent including 0, 0.5, 1.0, 1.5 and 2.0 kg were adopted. It was concluded that as the dose of C6F12O agent increased, the peak temperature of the long surface and bottom of the cells first increased slowly and then decreased rapidly. The results indicated that the C6F12O agent first shows a negative inhibitory effect, which is then transformed into an inhibitory effect as the dose increases. This inhibitory effect grew distinct gradually with an increase in dose. It was found that in a 47.5 x 21.5 x 16 cm3 module box, the appropriate dose of C6F12O agent was 9.42 g W-1 h-1. Accordingly, these results have implications in the fire suppression design for lithium-ion batteries.
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