4.7 Article

Hierarchical FeCo@MoS2 Nanoflowers with Strong Electromagnetic Wave Absorption and Broad Bandwidth

Journal

ACS APPLIED NANO MATERIALS
Volume 1, Issue 9, Pages 5179-5187

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsanm.8b01203

Keywords

FeCo@MoS2 composites; hierarchical nanoflowers; electromagnetic wave absorption; effective bandwidth; impedance matching

Funding

  1. National Natural Science Foundation of China [NSFC-11404284, 51571176, 51590881]
  2. Public Technology Application Research Projects of Zhejiang Province [2016C31008]
  3. National Key Research and Development Program [2016YFB0700902]

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Advanced electromagnetic (EM) wave absorbing materials are technologically important with extensively increasing utilization of EM waves in the gigahertz range. Hierarchical structure containing FeCo nanoparticles composited with MoS2 nanoflowers was developed as an effective EM wave absorber. Large surface area and sufficient voids provided by the MoS2 nanoflowers enable uniformly dispersed FeCo nanoparticles with single domain size for enhanced permeability and natural resonance. Existence of the large amount of the FeCo/MoS2 interfaces also improves the dielectric loss. The composite not only exhibits satisfactory impedance matching over a wide frequency range but also provides synergistic effect between magnetic and dielectric loss for effective dissipation of the wave energy. Excellent wave absorption performance was achieved for the composite with a maximum reflection loss (RL) of -64.64 dB at 14.4 GHz and a broad effective absorption bandwidth (RL < -10 dB) of 7.2 GHz at a small thickness of 2 mm. Consequently, a novel type of high-performance wave absorber was developed, and insights for the design of advanced EM wave absorbers with strong absorption capacity and broad effective bandwidth were provided.

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