Journal
NATURE MATERIALS
Volume 16, Issue 8, Pages 814-818Publisher
NATURE PUBLISHING GROUP
DOI: 10.1038/NMAT4896
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Funding
- VINN Excellence Center in research and innovation on Functional Nanoscale Materials (FunMat) by the Swedish Governmental Agency for Innovation Systems (VINNOVA)
- Swedish Government Strategic Research Areas in Materials Science on Functional Materials at Linkoping University [2009 00971]
- Swedish Foundation for Strategic Research through the Future Research Leaders 5 Program
- Synergy Grant FUNCASE, Functional Carbides and Advanced Surface Engineering
- e-Science Research Centre (SeRC)
- Swedish Research Council (VR) [2014-4750]
- European Research Council under the European Community [335383]
- Knut and Alice Wallenberg Foundation
- European Research Council (ERC) [335383] Funding Source: European Research Council (ERC)
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The large class of layered ceramics encompasses both van der Waals (vdW) and non-vdW solids. While intercalation of noble metals in vdW solids is known, formation of compounds by incorporation of noble-metal layers in non-vdW layered solids is largely unexplored. Here, we show formation of Ti3AuC2 and Ti3Au2C2 phases with up to 31% lattice swelling by a substitutional solid-state reaction of Au into Ti3SiC2 single-crystal thin films with simultaneous out-diffusion of Si. Ti3IrC2 is subsequently produced by a substitution reaction of Ir for Au in Ti3Au2C2. These phases form Ohmic electrical contacts to SiC and remain stable after 1,000 h of ageing at 600 degrees C in air. The present results, by combined analytical electron microscopy and ab initio calculations, open avenues for processing of noble-metal-containing layered ceramics that have not been synthesized from elemental sources, along with tunable properties such as stable electrical contacts for high-temperature power electronics or gas sensors.
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