Journal
3RD INTERNATIONAL SEMINAR ON CHEMISTRY: GREEN CHEMISTRY AND ITS ROLE FOR SUSTAINABILITY
Volume 2049, Issue -, Pages -Publisher
AMER INST PHYSICS
DOI: 10.1063/1.5082485
Keywords
Hidrocarbon liquid fuel; catalytic convertion; poly propylene plastic waste; Al-MCM-41
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Funding
- PDUPT Scheme of Grants
- Higher Education Directorate of Republic Indonesia
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Hydrocarbon liquid fuel (C8-C12) from poly propylene plastic waste has been successfully synthesized by catalytic conversion using Al-MCM-41 as catalyst. The Al-MCM-41 was characterized using SAXRD. Morphology of Al-MCM-41 surface was analyzed using TEM. The metals content were measured using XPS. The performance of Al-MCM-41 to adsorb and desorb nitrogen was monitored by GSA using BET model. The acidity of Al-MCM-41 was analyzed by FTIR by pyridine absorption method. Al-MCM-41 catalyst was used to convert polypropylene plastic waste in 200 mL catalytic convertion reactor. The Al-MCM-41 catalyst was used for three times and coded as sample A, B, and C. The results showed that sample A, B, and C produce hydrocarbon fraction (C8-C12) liquid fuel with a composition of 92.76; 91.92; and 90.58%, respectively. The repeated use of the catalyst causes a decrease in the composition of the hydrocarbon fraction (C8-C12) due to decrease of catalyst performance as observed by a TON (Turn Over Number) value which increased from 0.075%/gram to 0.156%/gram. Based on physical test i.e. boiling point, flash point, density, viscosity, and calorific value, it was proved that hydrocarbon fuels A, B and C have characteristics that in accordance with standard, premium gasoline, as specified in SNI 06-3506- 1994 and HIBER11Z international standards issued by Hibernia Petroleum Canada in 2016.
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