Journal
NANOSCALE
Volume 9, Issue 11, Pages 3986-3994Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6nr09818e
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Funding
- CAS Key Research Project of Frontier Science [Y62A0412B1]
- CAS Instrument Development Projects [Y31 M0112C1, Y5294512C1]
- Frontier Cross Project of National Laboratory for Molecular Sciences [051Z011BZ3]
- National Thousand Youth Talents Program [Y3297B1261]
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We report the synthesis of penicillamine-protected Ag-20 nanoclusters (NCs), with properties of high monodispersity, red fluorescence and water solubility. Full characterization of the Ag-20 NCs is addressed, along with first-principles optimization calculations, revealing the chemical composition and structure of the as-prepared Ag NCs within a molecular formula [Ag-20(DPA)(18)-H](-). Moreover, natural bond orbital (NBO) analysis demonstrates the charge-transfer interactions between the ligand and Ag atoms, and helps in understanding the origins of fluorescence of Ag-20 NCs related to the ligand-to-metal charge transfer (LMCT) mechanism. Further, fluorescence chemosensing of the Ag-20 NCs is demonstrated for tracing copper ions with high sensitivity and selectivity in aqueous solution.
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