Journal
NANOSCALE
Volume 9, Issue 11, Pages 3752-3756Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6nr09585b
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Funding
- National Natural Science Foundation of China [21575137, 21375076]
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In this Communication, cobalt phosphate (Co-Pi) has been successfully developed on a Co(CO3)(0.5)(OH).0.11H(2)O nanoarray (CCH NA) on Ti mesh in neutral phosphate-buffered solution (PBS) via in situ electrochemical surface derivation. The resulting core@shell structured CCH@Co-Pi NA/Ti exhibits remarkable activity toward water oxidation with the need of an overpotential of 460 mV to achieve a geometrical catalytic current density of 10 mA cm(-2) in 0.1 M PBS, with a high turnover frequency of and long-term electrochemical stability.
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