4.8 Article

Synthesis and chemical transformation of Ni nanoparticles embedded in silica

Journal

NANOSCALE
Volume 9, Issue 47, Pages 18959-18965

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c7nr06379b

Keywords

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Funding

  1. National Science Foundation [CBET-1605699, DMR-1056653, ECCS-1542015]
  2. Air Force Research Laboratory (AFRL) Materials and Manufacturing Directorate
  3. Air Force Office of Scientific Research [16RXCOR324]
  4. State of North Carolina

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Ni nanoparticles (NPs) catalyze many chemical reactions, in which they can become contaminated or agglomerate, resulting in poorer performance. We report deposition of silica (SiO2) onto Ni NPs from tetraethyl orthysilicate (TEOS) through a reverse microemulsion approach, which is accompanied by an unexpected etching process. Ni NPs with an average initial diameter of 27 nm were embedded in composite SiO2-overcoated Ni NPs (SiO2-Ni NPs) with an average diameter of 30 nm. Each SiO2-Ni NP contained a similar to 7 nm oxidized Ni core and numerous smaller oxidized Ni NPs with diameters of similar to 2 nm distributed throughout the SiO2 shell. Etching of the Ni NPs is attributed to use of ammonium hydroxide as a catalyst for deposition of SiO2. Aliquots acquired during the deposition and etching process reveal agglomeration of SiO2 and Ni NPs, followed by dissociation into highly uniform SiO2-Ni NPs. This etching and embedding process may also be extended to other core materials. The stability of SiO2-Ni NPs was also investigated under high-temperature oxidizing and reducing environments. The structure of the SiO2-Ni NPs remained significantly unchanged after both oxidation and reduction, which suggests structural durability when used for catalysis.

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