4.8 Article

Synthesis of Co/SiO2 hybrid nanocatalyst via twisted Co3Si2O5(OH)4 nanosheets for high-temperature Fischer-Tropsch reaction

Journal

NANO RESEARCH
Volume 10, Issue 3, Pages 1044-1055

Publisher

TSINGHUA UNIV PRESS
DOI: 10.1007/s12274-016-1364-7

Keywords

hybrid nanostructure; Fischer-Tropsch synthesis; thermal stability; metal silicate hydroxide; cobalt catalyst

Funding

  1. Research and Development Program of the Korea Institute of Energy Research (KIER) [B6-2439]
  2. Ministry of Trade, Industry and Energy (MOTIE) of the Republic of Korea [10050509]

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A cobalt-silica hybrid nanocatalyst bearing small cobalt particles of diameter similar to 5 nm was prepared through a hydrothermal reaction and hydrogen reduction. The resulting material showed very high CO conversion (> 82%) and high hydrocarbon productivity (similar to 1.0 g(HC)center dot g(-1) (cat)center dot h(-1)) with high activity (similar to 8.5 x 10(-5) mol(CO)center dot g (Co) (-1) center dot s(-1)) in the Fischer-Tropsch synthesis reaction.

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