Journal
NANO LETTERS
Volume 17, Issue 2, Pages 800-804Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.nanolett.6b04016
Keywords
Hard-soft exchange coupling; core-shell magnetic nanoparticle; shell-thickness control; surface canted spins; magnetic anisotropy; magnetic energy product
Categories
Funding
- Institute for Basic Science [IBS-R026-D1]
- Ministry of Science & ICT (MSIT), Republic of Korea [IBS-R026-D1-2017-A00] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
Ask authors/readers for more resources
The magnetic exchange coupling interaction between hard and soft magnetic phases has been important for tailoring nanoscale magnetism, but spin interactions at the core-shell interface have not been well studied. Here, we systematically investigated a new interface phenomenon termed enhanced spin canting (ESC), which is operative when the shell thickness becomes ultrathin, a few atomic layers, and exhibits a large enhancement of magnetic coercivity (H-c). We found that ESC arises not from the typical hard-soft exchange coupling but rather from the large magnetic surface anisotropy (K-s) of the ultrathin interface. Due to this large increase in magnetism, ultrathin core shell nanoparticles overreach the theoretical limit of magnetic energy product ((BH)(max)) and exhibit one of the largest values of specific loss power (SLP), which testifies to their potential capability as an effective mediator of magnetic energy conversion.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available